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The Georgia native, who won CMA Entertainer of the Year for the second straight year, sang an ovation-worthy rendition of the sultry "Strip It Down."

Zac Brown switched from banjo to acoustic guitar during his band's performance of "Beautiful Drug."

Bocephus opened the show alongside buddy Church with the debut of Williams' new single, "Are You Ready for the Country."

The Best New Artist nominee performed her breakthrough hit, "Love Me Like You Mean It."

The lauded violinist joined the Male Vocalist of the Year nominee on his poignant tune, "Riser."

The six-time Female Vocalist of the Year made the TV debut of "Bathroom Sink."

The hot country duo sang their sassy "Girl in a Country Song," which won the 2015 CMA award for Music Video of the Year.

The Best New Artist nominee performed the CMA-nominated "Take Your Time."

The longtime friends (and tour mates) received a standing ovation for two of their classic hits, Reba's "Why Haven't I" and Brooks & Dunn's "Play Something Country."

The Entertainer of the Year nominee strummed through his latest hit, "Save It for a Rainy Day."

In what was the most talked-about performance of the night, triple-winner Stapleton was joined by his pop powerhouse friend for a soulful, spine-tingling version of the George Jones classic, "Tennessee Whiskey." The two then, appropriately, sang Timberlake's "Drink You Away."

The 2015 CMA Vocal Group of the Year performed the 2015 Song and Single of the Year, "Girl Crush."

The Voice coach had everyone singing along to a lively version of his latest hit, "Gonna" at the CMAs.

Paisley's co-stars for his "Country Nation" performance were cheerleaders and college mascots from pretty much every team in the ACC, SEC, Big 10, Big 12 and Pac 12.

The CMA co-host strummed a guitar to her latest mega-hit, "Smoke Break."

The Best New Artist nominee and pop-rock band performed a mashup of Rhett's "Crash and Burn" and Fall Out Boy's "Uma Thurman," with a dance team sharing their stage.

The singer-songwriter played every bit the part of a "Dime Store Cowgirl" with her throwback performance on the CMAs.